Asymmetric Aerobic Epoxidation of Unfunctionalized Olefins Catalyzed by Optically Active α-Alkoxycarbonyl-β-ketoiminato Manganese(III) Complexes
- 1 February 1993
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 22 (2) , 327-330
- https://doi.org/10.1246/cl.1993.327
Abstract
Optically active N,N′-ethylenebis(α-alkoxycarbonyl-β-ketoimine) was found to be a new class of effective ligand of manganese(III) complex catalyst for the asymmetric aerobic epoxidation of simple olefins, such as 1,2-dihydronaphthalene derivatives, to afford the corresponding optically active epoxides with good to high enantioselectivities.Keywords
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