A Practical, Versatile Approach to Marine Furanosesquiterpenes. Synthesis of Siphonodictidine and Pleraplysillin-2
- 1 January 1990
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1990 (12) , 745-746
- https://doi.org/10.1055/s-1990-21235
Abstract
The first synthesis of siphonodictidine and a formal synthesis of pleraplysillin-2 have been accomplished in a highly concise and regiocontrolled manner by the use of 2-(tert-butyldimethylsiloxy)-3-methylfuran as the crucial building block, which was alkylated with 8-bromogeranyl acetate in the presence of silver trifluoroacetate.Keywords
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