Cobaltacarboranylacetylene 8,8'-(μ-CHC-CH2S)-(1,2-C2B9H10)2-3-Co(III): Synthesis, Characterization and Polymerization of New Substituted Acetylene
- 1 January 1996
- journal article
- Published by Institute of Organic Chemistry & Biochemistry in Collection of Czechoslovak Chemical Communications
- Vol. 61 (6) , 877-887
- https://doi.org/10.1135/cccc19960877
Abstract
Synthesis, structure and properties of 8,8'-(μ-propargylthio)bis(1,2-dicarbollido)cobaltate, 8,8'-(μ-CHC-CH2S)-(1,2-C2B9H10)2-3-Co(III), are described (NMR, IR, and UV spectra, mass spectrum, X-ray structure, dipole moment) and transformation of this acetylenic monomer into a π-conjugated homopolymer is reported.Keywords
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