Ring inversion of some 1,3-dioxanes
- 1 January 1966
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Transactions of the Faraday Society
- Vol. 62, 39-45
- https://doi.org/10.1039/tf9666200039
Abstract
Thermodynamic parameters have been determined for the chair-to-boat isomerization of 1,3-dioxane, its 2,2- and 5,5-dimethyl, and 2,2,5,5-tetramethyl-derivatives, in acetone or dichlorodi-fluoromethane solution in the temperature range 120–235°K. The significance of the results is discussed.Keywords
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