Synthesis of η-benzene-η-cyclohexa-1,3-diene derivatives of rhenium via reaction of rhenium atoms with benzene and cyclohexene: crystal structures of Re(η-C6H6)(η-C6H8)H and (η-C6H6)Re(µ-H)2Re(η-C6H8)2

Abstract
The reaction between rhenium atoms, benzene, and cyclohexene gives the compound Re(η-C6H6)(η-C6H8)H and the mixed valency dimer (η-C6H6)Re(µ-H)2Re(η-C6H8)2.

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