Microwave Spectrum of Silver Chloride

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Abstract
Pure rotational measurements have been made at about 800°C on the four naturally occurring AgCl species. The internuclear distance is re=2.28079±0.00004 Å. Stark-effect measurements give a dipole moment μ=5.70±0.15 D. Quadrupole hyperfine interactions for the 35Cl isotope give a coupling constant eqQ=−37.32±0.20 Mc/sec. An analysis is made of the pure rotational spectra in higher vibrational states. Values of the molecular constants for 107Ag35Cl are: Be=3687.04±0.09 Mc/sec, αe=17.855±0.011 Mc/sec, γe=0.019±0.004 Mc/sec, De=0.003±0.003 Mc/sec. Molecular constants are given for the remaining isotopic combinations of AgCl. The bond type of the gaseous AgCl molecule is discussed.

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