IR laser­induced thermolysis and UV laser­induced photolysis of 1,3­diethyldisiloxane: chemical vapour deposition of nanotextured hydridoalkylsilicones

Abstract
IR laser thermolysis and UV laser photolysis of gaseous 1,3-diethyldisiloxane proceed via different mechanisms: the former involves 1,1-H2 and ethene elimination, whereas the latter is dominated by 1,1-H2 and ethane elimination. The difference plays an important role in determining the composition of the solid nanotextured films deposited from the gas phase.

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