Abstract
High-resolution (6 km s−1 FWHM) observations of the interstellar λ3302 Na i doublet towards 11 southern early-type stars are presented. The analysis has resulted in much more accurate Na i column densities than those obtained from earlier studies of the (fully saturated) Na D lines. The λ3302 lines have low radial velocities (−15 ≲ υlsr ≲ + 10 km s−1) and are much simpler than the Na D and Ca ii profiles towards the same stars, generally occurring at those velocities previously identified with diffuse molecular clouds. Analysis of the Na i/Ca ii ratios in these components indicates that δCa ≈ −3 to −4 in the molecular clouds, implying that most of the Ca has been adsorbed on to the surfaces of interstellar grains. Lower Ca depletions are found in the less dense (non-molecular) clouds which are responsible for the additional absorption observed in the Na D and Ca K lines at both high and low velocities.

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