Catalysis of aldehyde imination by hydrogen bonding with a simple organic disulfonamide receptor

1 January 1999

journal article
Published by Royal Society of Chemistry (RSC) in Chemical Communications

No. 20,p. 2109-2110
https://doi.org/10.1039/a905838i

Abstract

The disulfonamide receptor 1 catalyzes imine formation from aldehyde and amine, apparently by binding the transition state for the rate-determining nucleophilic attack of amine on the aldehyde.

Keywords

IMINE
NUCLEOPHILIC
TRANSITION
ATTACK
DISULFONAMIDE
HYDROGEN BONDING
ALDEHYDE IMINATION
IMINATION BY HYDROGEN

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