Modified rotationally adiabatic model for rotational autoionization of dipole-bound molecular anions

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Abstract
Modifications are introduced to a rotationally adiabatic model developed and successfully applied by Clary to describe rotational autoionization of dipole-bound molecular anions. These modifications address branching ratios for forming neutrals in various final rotational states. They also produce rate-enhancement corrections to the original model in the neighborhoods of channel openings. Example calculations are presented and the essential ingredients of the corrections are tabulated in a manner that permits straightforward application to any linear or pseudolinear (i.e., symmetric top with ΔK=0) anion.
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