Cobalt-Catalyzed Intramolecular Heck-Type Reaction of 6-Halo-1-hexene Derivatives
- 1 June 2002
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 4 (13) , 2257-2259
- https://doi.org/10.1021/ol0261128
Abstract
Treatment of 6-iodo-1-hexene derivatives with trimethylsilylmethyl Grignard reagent in the presence of CoCl2(dppb) in refluxing THF affords Heck-type products, methylenecyclopentanes, in good yields.Keywords
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