3,3-Diethoxypropyl-lithium: a masked lithium propanal homoenolate
- 1 January 1987
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 425-426
- https://doi.org/10.1039/c39870000425
Abstract
3,3-Diethoxypropyl-lithium is prepared by lithiation of the corresponding chlorinated precursor with lithium naphthalenide at –78 °C; the reaction of this masked propanal homoenolate with different electrophilic reagents [H2O, D2O, (PhCH2)2S2, n-C3H7CHO, PhCHO, n-C7H15CHO, PhCHNPh] leads to the corresponding mono- and bi-functionalized compounds.Keywords
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