Synthesis of 2,4,6-tri-t-butylthiobenzaldehyde, the first stable thiobenzaldehyde

Abstract
The title compound, an extremely stable thiobenzaldehyde, was prepared by the reaction of 2,4,6-tri-t-butylphenyl-lithium with O-ethyl thioformate or the reaction of 2,4,6-tri-t-butylbenzaldehyde hydrazone with disulphur dichloride.

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