Synthesis of 1,1-Bis(Phenylthio)-2-Methyl-1,3-Butadiene
- 1 January 1978
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 8 (2) , 87-92
- https://doi.org/10.1080/00397917808062100
Abstract
During the course of our studies on (2.3) sigmatropic rearrangements, various allylic and benzylic sulfides have been treated with chloromethylthiobenzene in basic media. Aqueous sodium hydroxide (50%) in the presence of a phase transfer agent was the most convenient medium for generating in situ the ylids of β, γ-unsaturated sulfonium salts containing a phenylthio group on the anionic carbon atom 1.Keywords
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