Inadequacy of Ehrenfest’s theorem to characterize the classical regime
- 1 October 1994
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 50 (4) , 2854-2859
- https://doi.org/10.1103/physreva.50.2854
Abstract
The classical limit of quantum mechanics is usually discussed in terms of Ehrenfest’s theorem, which states that, for a sufficiently narrow wave packet, the mean position in the quantum state will follow a classical trajectory. We show, however, that that criterion is neither necessary nor sufficient to identify the classical regime. Generally speaking, the classical limit of a quantum state is not a single classical orbit, but an ensemble of orbits. The failure of the mean position in the quantum state to follow a classical orbit often merely reflects the fact that the centroid of a classical ensemble need not follow a classical orbit. A quantum state may behave essentially classically, even when Ehrenfest’s theorem does not apply, if it yields agreement with the results calculated from the Liouville equation for a classical ensemble. We illustrate this fact with examples that include both regular and chaotic classical motions.Keywords
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