Models for enzyme–substrate complexes: kinetics of hydrolysis of bicyclic immonium ether perchlorates
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 15,p. 900-901
- https://doi.org/10.1039/c29700000900
Abstract
The rates of hydrolysis of bicyclic immonium ether perchlorates have been measured and the results have been interpreted in terms of unstable cyclol intermediates; on reaction with sodium methoxide the perchlorates yielded bicyclic lactam acetals.Keywords
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