X-Ray structural and Raman data, including remarkable resonance Raman effects, for quadruple molybdenum-to-molybdenum bonds
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 12,p. 399-400
- https://doi.org/10.1039/c39730000399
Abstract
The Mo2(SO4)4 4– ion has been studied crystallographically and found to have a very short (2·110 Å) Mo–Mo bond; the Raman spectra of this and other Mo2 4+ complexes exhibit strong bands (“Mo–Mo stretching”) in the range 345–406 cm–1 with Mo2Cl8 4– compounds showing remarkable resonance Raman enhancements up to the 3rd overtone when irradiated at 4880 Å.Keywords
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