A novel type of photosubstitution of [fac-Re(bpy)(CO)3Br](bpy = 2,2′-bipyridine) with P(OR)3in the presence of triethylamine: efficient formation of [Re(bpy)(CO)2{P(OR)3}2]+Br–
- 1 January 1991
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 787-788
- https://doi.org/10.1039/c39910000787
Abstract
Photochemical ligand substitution of [fac-Re(bpy)(CO)3Br] with P(OEt)3 in the presence of triethylamine quantitatively gave [Re(bpy)(CO)2{P(OEt)3}3]+Br– without the intervention of a mono-substituted product.Keywords
This publication has 11 references indexed in Scilit:
- Remarkable Solvent Effects on the Photocatalytic Behavior of [fac-Re(bpy)(CO)3Br] (bpy = 2,2′-bipyridine). Selective Hydrogen Evolution in Ether Solvents in the Presence of TriethylamineChemistry Letters, 1989
- Further studies of the photoinduced reduction of carbon dioxide mediated by tricarbonylbromo(2,2'-bipyridine)rhenium(I)Organometallics, 1987
- Hydrogen photoproduction by visible light irradiation of an organorhenium catalyst incorporated into aqueous suspensions of hectoriteJournal of the Chemical Society, Chemical Communications, 1987
- Photochemical and Electrochemical Reduction of Carbon Dioxide to Carbon Monoxide Mediated by (2,2′‐Bipyridine)tricarbonylchlororhenium(I) and Related Complexes as Homogeneous CatalystsHelvetica Chimica Acta, 1986
- Luminescence and redox reactions of the metal-to-ligand charge-transfer excited state of tricarbonylchloro-(polypyridyl)rhenium(I) complexesJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1986
- A mechanistic investigation of the photoinduced reduction of carbon dioxide mediated by tricarbonylbromo(2,2'-bipyridine)rhenium(I)Organometallics, 1985
- One- and two-electron pathways in the electrocatalytic reduction of CO2by fac-Re(bpy)(CO)3Cl (bpy = 2,2′-bipyridine)Journal of the Chemical Society, Chemical Communications, 1985
- Efficient photochemical reduction of CO2to CO by visible light irradiation of systems containing Re(bipy)(CO)3X or Ru(bipy)32+–Co2+combinations as homogeneous catalystsJournal of the Chemical Society, Chemical Communications, 1983
- New mechanism for photosubstitution of organometallic complexes. Generation of substitutionally labile oxidation states by excited-state electron transfer in the presence of ligandsJournal of the American Chemical Society, 1981
- A new process for sensitization of ketone photoreduction: exploitation of low-lying metal-to-ketone charge-transfer excited statesJournal of the American Chemical Society, 1980