Use of Electrochemiluminescence in the Measurement of Mass Transfer Rates

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Abstract
When a potential is applied between two platinum electrodes immersed in a flowing chemiluminescent solution, a blue glow appears at the surface of the anode. An electrochemical system suitable for generating the glow is described. Experimental results are presented showing the effects of the parameters on the intensity of the glow. It is shown that for a given potential and a given solution the light intensity is governed solely by mass transfer of the chemiluminescent substance to the surface of the anode.

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