Silicone grease as a precursor to a pseudo crown ether ligand: crystal structure of [K+]3[K(Me2SiO)7+][InH(CH2CMe3)3–]4
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 20,p. 1577-1578
- https://doi.org/10.1039/c39930001577
Abstract
The crystallization of K[InH(CH2CMe3)3] from heptane in the presence of silicone grease led to the formation of the title compound, in which one potassium cation is surrounded by a planar cyclo-(Me2SiO)7 ligand; K+⋯ O distances range from 2.86(3) to 2.99(4)Å.Keywords
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