Selective inclusion of phenylenediamine isomers by 1, 1-bis(4-hydroxyphenyl)cyclohexane

Abstract
The title host compound includes para- and ortho-phenylenediamine. The structures of the clathrates are stabilized by a network of hydrogen bonds. Competition experiments in solution and suspension show that the para-isomer is preferentially enclathrated. The inclusion compounds can also be formed by solid-solid reactions.

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