Associated Complex Formation in a Binary Solution and the Concentration Fluctuation: The Chloroform–Diethyl Ether System
- 1 November 1976
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 49 (11) , 2988-2994
- https://doi.org/10.1246/bcsj.49.2988
Abstract
The relations between the associated complex formation and the concentration fluctuation in a binary solution were derived. The concentration fluctuation of a chloroform–diethyl ether system was determined by observing light-scattering spectra at various concentrations. The theoretical values of the concentration fluctuation of this system were calculated from the proposed relation by the use of the shape and the number population of the associated complex, as determined from the infrared absorption intensity measurements. The observed and calculated concentration fluctuations agreed quite well.Keywords
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