Analysis of Crystal Structure of an Y-Ba-Cu Oxide

Abstract
Results of the analyses on crystal structure and chemical composition of dark-green crystals mainly found in an Y-Ba-Cu oxide specimen which shows high-T c superconductivity are reported. Crystal structure is investigated by the electron diffraction method and is determined to be orthorhombic with lattice parameters a=1.22 nm, b=0.561 nm and c=0.714nm, and with a space group Pnma (No. 62) or Pna21 (No. 33). Expected d-values are presented and are successfully compared with the X-ray powder diffraction spectrum obtained from this oxide. Chemical composition is analyzed by the EPMA method and is determined to be Y2BaCuO5-y for the oxide.

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