Zur Analyse der Rotationsspektren in torsionsangeregten Zuständen von Molekülen mit zwei Methylgruppen/A Contribution to the Analysis of Rotational Spectra in Torsional Excited States of Molecules with two Methyl Tops
Open Access
- 1 May 1973
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung A
- Vol. 28 (5) , 750-758
- https://doi.org/10.1515/zna-1973-0536
Abstract
An analysis of the rotational spectra in torsional excited states is given for propane, dimethylsilane and dimethylsulfide. The analysis is based on the Hamiltonian for the quasi-rigid model. The potential barrier V3 and one additional potential coefficient V′12 were determined. The splitting within the multipletts could be reproduced, but not the spacing between them.Keywords
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