Oxovanadium(IV) Complex-mediated Catalysis in Mukaiyama-type Aldol Additions
- 1 June 1999
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1999 (6) , 816-818
- https://doi.org/10.1055/s-1999-2729
Abstract
Condensation of vanadyl sulfate with 2,2′-biphenol in the presence of N-containing ligands provides oxovanadium(IV) complexes which serve as efficient catalysts in Mukaiyama aldol reactions to afford aldol products in 52-100% yields with diastereoselectivities of up to 90/10 (anti/syn).Keywords
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