Chemiluminescence measurements of the N+2, N++H2O charge transfer systems at suprathermal energies: Direct probe of the dynamics of large cross section charge transfer processes
- 15 December 1990
- journal article
- letter
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 93 (12) , 9189-9191
- https://doi.org/10.1063/1.459208
Abstract
The chemiluminescence from suprathermal N+2–H2O and N+–H2O collisions is studied using a new experiment. Intense H2O+Ã 2A1–X̃ 2B1 emission is observed from the N+2 +H2O charge transfer whereas no emissions are detected from the N+–H2O system. OH A 2Σ+–X 2Π emission originating from the N+2+H2O atom pickup channel is also observed.Keywords
This publication has 18 references indexed in Scilit:
- Theoretical state-to-state inelastic cross sections for collisions of Ar+(2P3/2, 2P1/2) with N2The Journal of Chemical Physics, 1988
- Theoretical state-to-state charge transfer cross sections for collisions of Ar+ (2P3/2, 2P1/2) with N2The Journal of Chemical Physics, 1987
- A crossed-beam study of the reactive and unreactive scattering of Ar+(2P
3 2 ) and Ar+(2P1 2 ) by N2 at low energiesChemical Physics, 1987 - A simple determination of the potential energy curves and couplings for long-range charge-transfer reactions. Application to the system (ArN2)+Chemical Physics, 1986
- A time-dependent quantal analysis of vibronic excitation via charge transfer in ion-molecule collisionsChemical Physics, 1985
- State-selected ion-molecule reactions: N2+(X, v″), N2+(A, v′) + Ar → N2 + Ar+Chemical Physics, 1984
- State selected ion–molecule reactions by a TESICO technique. VIII. Vibronic-state dependence of the cross sections in the reaction NO+(a 3Σ+, v ; b 3Π, v)+Ar → NO+Ar+The Journal of Chemical Physics, 1983
- State selected ion–molecule reactions by a TESICO technique. VI. Vibronic-state dependence of the cross sections in the reactions O+2(X 2Πg, v; a 4Πu, v)+H2→ O2H++H, H+2+O2The Journal of Chemical Physics, 1982
- State selected ion–molecule reactions by a TESICO technique. V. N2+(v)+Ar→N2+Ar+The Journal of Chemical Physics, 1982
- State selected ion–molecule reactions by a TESICO technique. IV. Relative importance of the two spin-orbit states of Ar+ in the charge transfer reactions with N2 and COThe Journal of Chemical Physics, 1982