Intramolecular Diels-Alder Reaction of Vinylsulfonates Possessing an Acyclic Diene Moiety

1 January 1993

journal article
letter
Published by Georg Thieme Verlag KG in Synlett

Vol. 1993 (06) , 399-400
https://doi.org/10.1055/s-1993-22469

Abstract

Vinylsulfonates 2 possessing an acyclic diene moiety undergo intramolecular cycloaddition in refluxing toluene. The diastereoselectivity of this process is substantially enhanced if the diene substituent R² is larger than hydrogen.

Keywords

VINYLSULFONATES
ACYCLIC DIENE
DIENE MOIETY
SUP
EM CLASS
REFLUXING TOLUENE
MOIETY UNDERGO
SUBSTANTIALLY ENHANCED
UNDERGO INTRAMOLECULAR

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