Nuclear magnetic resonance and Mössbauer spectra of some organotin anions
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 11,p. 1087-1092
- https://doi.org/10.1039/dt9750001087
Abstract
1 H N.m.r. spectra of SnH4, [Me3 –xSnHx]–, [Ph3 –xSnHx]–, and [(PhCH2)2SnH]– have been obtained in liquid ammonia and the nature of the species present in solution is discussed. Evidence to support the presence of 2-ions in solution has not been obtained. Mössbauer data on Na[SnPh3] confirm that both contact and solvent-separated ion pairs are present together in dimethoxyethane solutions and that their Mössbauer parameters are δ 1·20, Δ= 0·0 and δ= 2·14, Δ= 1·87 mm s–1, respectively.Keywords
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