Anionic oligomerisation of hexafluoropropene: fission of a carbon–carbon bond by fluoride ion
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 21,p. 1444-1446
- https://doi.org/10.1039/c29700001444
Abstract
Fluoride ion catalyses the oligomerisation of hexafluoropropene, and treatment of the individual dimers and trimers with fluoride ion leads to isomerisation and, in the case of one trimer, to fission of a carbon-carbon bond to give a dimer and the heptafluoro-isopropyl carbanion.Keywords
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