Solvent-free one-pot rapid synthesis of 3-carboxycoumarins

Abstract
Reaction of 2-hydroxy- or 2-methoxy-substituted benzaldehydes or acetophenones with Meldrum’s acid in the presence of environmentally-friendly catalysts, like natural kaolinitic clays, EPZ10 and EPZG, without solvent using focused microwaves afforded 3-carboxycoumarins in excellent yields.

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