Rapid Fluorodesilylation of Aryltrimethylsilanes Using Xenon Difuoride: An Efficient New Route to Aromatic Fluorides

1 January 1993

journal article
letter
Published by Georg Thieme Verlag KG in Synlett

Vol. 1993 (10) , 753-755
https://doi.org/10.1055/s-1993-22596

Abstract

The reaction of aryltrimethylsilanes (1) with xenon difluoride in C₆F₆ at room temperature results in the rapid and clean formation of arylfluorides (2). Evidence that the reaction proceeds via arylradicals (8) is presented.

Keywords

ARYLTRIMETHYLSILANES
EM CLASS
NEW ROUTE
USING XENON
EFFICIENT NEW
RAPID FLUORODESILYLATION
AROMATIC FLUORIDES
CLEAN FORMATION
XENON DIFUORIDE

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