Enantio-controlled route to the furofuran lignans: the total synthesis of (–)-sesamolin, (–)-sesamin, and (–)-acuminatolide
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 189-191
- https://doi.org/10.1039/c39880000189
Abstract
The first enantio-controlled route to the furofuran lignans, (–)-sesamolin, (–)-sesamolin, and (–)-acuminatolide, has been developed starting from diethyl L-tartrate by employing an intramolecular hetero-Diels–Alder reaction as the key step.Keywords
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