Synthesis, structure, and facile oxidation of a novel 1,1′-bis(N,N-dimethylaminomethyl)ferrocene bridged diplatinum complex
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 8,p. 601-603
- https://doi.org/10.1039/c39900000601
Abstract
The reaction of cis-PtCl2(dmso)2(dmso = dimethylsulphoxide) with the ferrocenyl amine (η5-Me2NCH2C5H4)2Fe yields the readily oxidised, cyclometallated derivative [η5-PtCl(dmso)Me2NCH2C5H3]2Fe through the intermediary of the complex [η5-trans-PtCl2(dmso)Me2NCH2C5H4]2Fe; an X-ray study of the cyclometallated species shows that the ferrocenyl bridged Pt atoms are located one above the other at a separation of 4.285(5)Å.Keywords
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