SYNTHESIS OF A CHIRAL 1,1,3-TRIMETHYLCYCLOHEXANE DERIVATIVE FROM d-CAMPHOR: A POTENT KEY BUILDING BLOCK FOR ENT-TAXANE-TYPE DITERPENOIDS
- 5 August 1980
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 9 (8) , 1001-1004
- https://doi.org/10.1246/cl.1980.1001
Abstract
A chiarl 1,1,3-trimethylcyclohexane derivative (12), which is a potent key building block for synthesis of ent-taxane-type diterpenoids, has been prepared from d-camphor (2) through a conversion pathway which involves a novel ring enlargement reaction of a 1,1,2-trimethylcyclopentane derivative (3).This publication has 4 references indexed in Scilit:
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