The neighbouring group participation by the carbonyl group in the hydrolysis of flexible keto-esters and its inhibition when substrates are placed inside the helical cavities of amylose
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 71-72
- https://doi.org/10.1039/c39850000071
Abstract
Anchimeric assistance by carbonyl groups in the hydrolysis of flexible keto-esters (2)–(4) is completely inhibited when these substrates are encapsulated inside the cavities of amylose.Keywords
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