Synthesis, spectroscopic properties and molecular structure of the paramagnetic complex [(η5-3,5-di-tert-butyl-1,2,4-triphosphacyclopentadienyl)(η5-2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienyl)]vanadium(II)
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1659-1660
- https://doi.org/10.1039/c39950001659
Abstract
Cocondensation of vanadium vapour with the phosphaalkyne ButCP affords the paramagnetic complex [V(η5-P3C2But 2)(η5-P2C3But 3)], whose molecular structure is determined by a single crystal X-ray diffraction study.Keywords
This publication has 15 references indexed in Scilit:
- 1,3,5,7‐Tetraphosphabarrelene: A New Cyclic Phosphaalkyne TetramerAngewandte Chemie International Edition in English, 1995
- Synthesis and Characterization of the First Compounds Containing a Stable Phosphirenyl Cation: Crystal and Molecular Structure of [Ni(η3‐PC2tBu2)(η5‐P3C2tBu2)W(CO)5]Angewandte Chemie International Edition in English, 1994
- Synthesis and molecular structure of tris(η4-2,4-di-tert-butyl-1,3-diphosphacyclobutadiene)molybdenum(0)Journal of the Chemical Society, Chemical Communications, 1994
- Hexa-phosphorus analogues of metallocenes: synthesis of the first paramagnetic sandwich complex containing two η51,2,4-triphosphacyclopentadienyl rings. Crystal and molecular structures of [Cr(η5-C2But2P3)2]Journal of Organometallic Chemistry, 1988
- Coordination chemistry of compounds containing phosphorus-carbon multiple bondsChemical Reviews, 1988
- λ 3 ‐1,3‐Diphosphacyclobutadiene‐Cobalt Complexes by Cyclodimerization of λ 3 ‐PhosphaalkynesEuropean Journal of Inorganic Chemistry, 1988
- Reaktive π-Komplexe der elektronenreichen Übergangsmetalle, IV. Cyclisierungsreaktionen von t-Butylphosphaacetylen an π-Areneisen-KomplexenJournal of Organometallic Chemistry, 1987
- First structural characterisation of penta- and hexa-phosphorus analogues of ferrocene. Synthesis, crystal and molecular structure of the air-stable, sublimable iron sandwich compounds [Fe(η5-C2R2P3)2], and [Fe(η5-C3R3P2)(η5-C2R2P3)](R = But)Journal of the Chemical Society, Chemical Communications, 1987
- 1,3‐Diphosphacyclobutadienecobalt(I) Complexes from PhosphaalkynesAngewandte Chemie International Edition in English, 1986
- First example of cyclodimerisation of a phospha-alkyne to a 1,3-diphosphacyclobutadiene. Syntheses of complexes of the type [M(η5-C5R5){η4-(ButCP)2}] R = H or Me; M = Co, Rh, or Ir): crystal and molecular structure of η5-pentamethylcyclopentadienyl-2,4-di-t-butyl-1,3-diphosphacyclobutadienecobalt(I), [Co(η5-C5Me5){η4-(ButCP)2}]Journal of the Chemical Society, Chemical Communications, 1986