Reaktionen von Halogeno-Phosphin-Metall(II)-Komplexen mit organischen Aziden. Phosphatriazen-Kobalt(II) -Komplexe / Reactions of Halogeno Phosphine Metal(II) Complexes with Organic Azides. Phosphatriazene Cobalt(II) Complexes
Open Access
- 1 May 1977
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Naturforschung B
- Vol. 32 (5) , 528-532
- https://doi.org/10.1515/znb-1977-0509
Abstract
The phosphine complexes Co(PR3)2X2 (X = Cl, Br; R = Et, Ph, C6H11) react with furoylazide (furN3) at 25 °C to give the phosphinimine compounds Co(furN=PR3)2X2. At lower temperatures the intermediate complex Co[furN3P(C6H11)3]Br2 • Et2O with phosphatriazene as ligand could be isolated.Keywords
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