Abstract
A three-dimensional X-ray diffraction analysis of BaS2O3 · H2O was based on 523 symmetry-independent reflexions. The structure was refined by full-matrix least-squares to an R (excluding zero-weight data) of 0.065 for 492 reflexions. The structural details of the earlier studies are confirmed. An analysis of the thermal motions of the individual nonhydrogen atoms was made on the basis of thermal vibration ellipsoids and molecular geometry.

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