Regioselectivity in the reactions of aryltri-isopropoxytitanium with pyrimidinones.
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 9,p. 1997-1999
- https://doi.org/10.1039/p19850001997
Abstract
Complete regioselectivity is observed in the 1 : 1-adduct formation between aryltri-isopropoxytitanium reagents and pyrimidin-2(1H)ones; the new carbon–carbon bond is formed at C-4. Dehydrogenation gives the arylated, fully conjugated heterocycle.This publication has 2 references indexed in Scilit:
- Organopalladium Compounds in Organic Synthesis and in CatalysisPublished by Elsevier ,1982
- Pyrimidones 1. Synthesis of some 1‐substituted‐5‐aryl‐ and (4,5‐diaryl)‐2(1H)pyrimidonesJournal of Heterocyclic Chemistry, 1979