(5R,8S,10R)-6-Alkyl-8-ergolinecarboxylic acids and some of their derivatives

Abstract
(5R,8S,10R)-6-Methyl-8-methoxycarbonylergoline (VIIb) was converted via Ib and IIb into its 6-analogues IIIb-VIb, which, in turn, were converted into acids IIIa-VIa and hydrazides IIIc-VIc. Some of the esters prepared, mainly IVb, had inhibitory effects on the secretion of prolactin in rats.

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