Solid state unidirectional photoisomerization of (β-substituted ethyl)bis(dibubstituted glyoximato)(L)cobalt(III) to the α-substituted ethyl complexes (L = pyridine or primary amine)
- 1 January 1985
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 21-23
- https://doi.org/10.1039/c39850000021
Abstract
Photoisomerization of β-cyanoethyl-and β(methoxycarbonyl)ethyl-bis(disubstituted glyoximato)(L)cobalt(III)(L = pyridine or primary amines) to the α-substituted ethyl complexes occurred in the solid state, but the reverse (α→β) isomerization was not observed, despite the fact that Co–C bond cleavage occurred.Keywords
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