Heteropolyanions in non-polar solvents. Metalloporphyrin-like oxidation of chromium(III) to chromium(V) by iodosylbenzene
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1186-1188
- https://doi.org/10.1039/c39860001186
Abstract
Solutions of [SiMo11O39Cr(OH2)]5– and [SiW11O39Cr(OH)]6– in toluene, benzene, or acetonitrile react with iodosylbenzene to yield the corresponding oxochromium(V) species.Keywords
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