- and -relaxations in supercooled binary liquids
- 18 November 1996
- journal article
- Published by IOP Publishing in Journal of Physics: Condensed Matter
- Vol. 8 (47) , 9581-9586
- https://doi.org/10.1088/0953-8984/8/47/066
Abstract
The - and -relaxations in a disparate-size binary liquid near the glass transition have been investigated within a mode-coupling theory. We focus our attention on the - and -peaks in the frequency-dependent susceptibility and their dependence on the concentrations of big and small particles. For the 1:1 mixture of big and small particles (size ratio = 0.2), a large peak appears in the susceptibility of the small particles in the frequency range of the -relaxation, which corresponds to the fast relaxation of the small particles within the random potential produced by the big particles. The intensity of this peak grows further as the concentration of the small particles is decreased. For large , on the other hand, the peak becomes lower than the -peak and the susceptibility is similar to that of a one-component liquid.Keywords
This publication has 6 references indexed in Scilit:
- Self-Diffusion in Supercooled Binary LiquidsPhysical Review Letters, 1995
- Relaxation processes in supercooled liquidsReports on Progress in Physics, 1992
- Phase separation of asymmetric binary hard-sphere fluidsPhysical Review Letters, 1991
- Glass transition of two-component liquids. I. The Debye-Waller factorsPhysical Review A, 1991
- Dynamics of a Lennard-Jones system close to the glass transitionPhysical Review A, 1986
- Exact Solution of Generalized Percus-Yevick Equation for a Mixture of Hard SpheresPhysical Review B, 1964