Stereospecific introduction of an asymmetric centre at C-6 in a glycoside
- 1 January 1984
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 659-661
- https://doi.org/10.1039/c39840000659
Abstract
Stereospecific addition of Me2Cu(CN)Li2 to a bicyclic conjugated lactone, derived from D-glucose viaan intram olecular Wadsworth–Emmons reaction, affords a rational route to introduce a chiral centre at C-6 on the glucose skeleton.Keywords
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