µ-Carbido-bridged iron phthalocyanine dimers: synthesis and characterization
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 46-47
- https://doi.org/10.1039/c39880000046
Abstract
The synthesis of the µ-carbido species of formula (pcFe)2C (pc = phthalocyaninato dianion) has been accomplished by reaction of pcFe with Cl4, while reaction of (pcFe)2C with 1-methylimidazole produces an adduct of formula [(1-Meim)pcFe]2C; on the basis of i.r. and visible spectra and single crystal X-ray data, both species have been characterized as µ-carbido-bridged Fe dimers.Keywords
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