Synthesis of putative precursors of ecdysone. Part 3. Synthesis of 3β, 14α, 25-trihydroxy-5β-cholest-7-en-6-one
- 1 January 1988
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 8,p. 2353-2363
- https://doi.org/10.1039/p19880002353
Abstract
We describe here the first synthesis of 2, 22-dideoxyecdysone (3)(3β, 14α, 25-trihydroxy-5β-cholest-7en-6-one), a putative precursor in the biosynthesis of ecdysone (1). All the intermediates synthesized have a cis junction of the A/B rings (5β-H configuration).This publication has 3 references indexed in Scilit:
- In vitro studies on potential selective and irreversible inhibitors of enzymes involved in the biosynthesis of ecdysonePesticide Biochemistry and Physiology, 1987
- Synthesis of a labelled putative precursor of ecdysone—IIInsect Biochemistry, 1987
- Adult ovaries of contain the sequence of biosynthetic intermediates for ecdysoneLife Sciences, 1978