Approaches to cytochalasan synthesis: macrocycle formation using an intramolecular Diels–Alder reaction

1 January 1978

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 11,p. 474-475
https://doi.org/10.1039/c39780000474

Abstract

Thermolysis of the long-chain diene-anhydride (3) gives a mixture of macrocyclic lactones (2; 27%) and (10; 5%)via an intramolecular Diels–Alder reaction.

Keywords

CYTOCHALASAN SYNTHESIS
DIENE
LACTONES
THERMOLYSIS
ANHYDRIDE
MACROCYCLE FORMATION USING
DIELS

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