On the theory of pseudocontact N.M.R. shifts due to lanthanide complexes
- 1 December 1973
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 26 (6) , 1389-1396
- https://doi.org/10.1080/00268977300102561
Abstract
The pseudocontact N.M.R. shifts due to complexes of lanthanide ions are considered in a crystal field theoretical framework including all the states J, M of an L-S manifold and an arbitrary set of crystal field parameters. Deviations from Bleaney's earlier theory are shown to be of the order of 20 per cent when the higher crystal field parameters are added.Keywords
This publication has 10 references indexed in Scilit:
- EVIDENCE FOR THE PRESENCE OF CONTACT TERM CONTRIBUTION TO LANTHANIDE-INDUCED ISOTROPIC SHIFTS IN 13C AND 19F NMR SPECTRA OF ALIPHATIC COMPOUNDS: CAUTION FOR APPLICATIONS OF LANTHANIDE SHIFT REAGENTSChemistry Letters, 1972
- Origin of lanthanide nuclear magnetic resonance shifts and their usesJournal of the Chemical Society, Chemical Communications, 1972
- A theoretical study of the 14N and 17O N.M.R. shifts in lanthanide complexesAustralian Journal of Chemistry, 1972
- Contact effects in nuclear magnetic resonance spectra with lanthanide shift reagentsJournal of the Chemical Society, Chemical Communications, 1972
- Lanthanide shift reagents. SurveyJournal of the American Chemical Society, 1971
- Quantitative Determination of Mononucleotide Conformations in Solution using Lanthanide Ion Shift and Broadening NMR ProbesNature, 1971
- Isotropic NMR shifts in transition metal complexes: The calculation of the fermi contact and pseudocontact termsJournal of Magnetic Resonance (1969), 1970
- Paramagnetic shifts in solutions of cholesterol and the dipyridine adduct of trisdipivalomethanatoeuropium(III). A shift reagentJournal of the American Chemical Society, 1969
- Theory of Spin-Orbit Coupling in Atoms. IIIPhysical Review B, 1964
- Oxygen-17 NMR Shifts in Aqueous Solutions of Rare-Earth IonsThe Journal of Chemical Physics, 1962