The photoisomerisation of α-tropolone
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 19,p. 1265b-1266
- https://doi.org/10.1039/c2970001265b
Abstract
α-Tropolone photoisomerises in hexane via 5-hydroxybicyclo[3,2,0]hepta-2,6-dien-4-one (III) to a mixture of bicyclo[3,2,0]hept-2-ene-4,6-dione and bicyclo-[3,2,0]hept-2-ene-4,7-dione; the hydroxy-ketone (III) is also formed when α-tropolone is irradiated in water and in methanol.Keywords
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