Studies on the Chemical Structure of Colistin

Abstract
The full structure of colistin B was determined as IOA→(α)DAB→Thr→(α)DAB→(α) cyclo→(γ)DAB→(α)DAB→D-Leu→L-Leu→(α)DAB→(α)DAB→Thr→ with combination of enzymatic digestion and acid partial hydrolysis. The structure is identical to that of colistin A, with the exception that colistin B contains isoöctanoic acid instead of 6-methyl-octanoic acid in colistin A.

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